B—N bond cleavage by cobalt(II) in acetato(3,5-diphenylpyrazole)[tris(3,5-diphenylpyrazolyl)borato]cobalt(II)
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منابع مشابه
Synthesis of Zinc Dimethyldithiocarbamate by Reductive Disulfide Bond Cleavage of Tetramethylthiuram Disulfide in Presence of Zn2+
The zinc(II) complex [Zn2(dmdtc)2(μ-dmdtc)2] has been synthesized directly from thiram ligand, containing a disulfide bond {dmdtc = N,N-dimethyldithiocarbamate; thiram = N,N-tetramethylthiuram disulfide}, and characterized by elemental analysis and spectroscopic methods. Surprisingly thiram, undergoes a reductive disulfide bond scission upon reaction with Zn2+ in methanolic media to give the [Z...
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Addition of an excess of t-butyl isocyanide to solid Mo2 (0, CCF3 )4 or MO?_ (0, CMe)4 gives (t-BuNC), Mo(Oz CCF3 )* or (t-BuNC), Mo(Oz CMe), , respectively. The quadruple bond in K4 MO* Cl8 or Cl4 MO, (n-Bus P)4 also can be cleaved by an excess of t-butyl isocyanide to yield (t-BuNC), MoCl, _ The anionic ligands can be exchanged with ammonium hexafluorophosphate in presence of excess t-BuNC to...
متن کاملsynthesis of zinc dimethyldithiocarbamate by reductive disulfide bond cleavage of tetramethylthiuram disulfide in presence of zn2+
the zinc(ii) complex [zn2(dmdtc)2(μ-dmdtc)2] has been synthesized directly from thiram ligand, containing a disulfide bond {dmdtc = n,n-dimethyldithiocarbamate; thiram = n,n-tetramethylthiuram disulfide}, and characterized by elemental analysis and spectroscopic methods. surprisingly thiram, undergoes a reductive disulfide bond scission upon reaction with zn2+ in methanolic media to give the [z...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section C Crystal Structure Communications
سال: 2005
ISSN: 0108-2701
DOI: 10.1107/s0108270105014277